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  On the kinetic modeling of electron attachment to polyatomic molecules.

Nikitin, E. E., & Troe, J. (2012). On the kinetic modeling of electron attachment to polyatomic molecules. Molecular Physics, 110(15-16), 1627-1635. doi:10.1080/00268976.2012.663941.

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 Urheber:
Nikitin, E. E.1, Autor           
Troe, J.1, Autor           
Affiliations:
1Emeritus Group of Spectroscopy and Photochemical Kinetics, MPI for Biophysical Chemistry, Max Planck Society, ou_578625              

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Sprache(n): eng - English
 Datum: 2012-03-132012
 Publikationsstatus: Erschienen
 Seiten: -
 Ort, Verlag, Ausgabe: -
 Inhaltsverzeichnis: The description of electron attachment to neutral target molecules by kinetic modeling is compared with dynamical two-state and multi-state zero range potential treatments. It is shown that kinetic modeling, combining electron capture theory with empirical (experimentally fitted) electron–phonon coupling and inelastic scattering factors, approaches the results from the dynamical models provided that the coupling of the electronic wave function for attachment to the ground and excited vibrational states of the neutral is not too large. Strong coupling effects, e.g. resulting in large cusps of the cross sections, are not accounted for by the modeling with separated kinetic steps.
 Art der Begutachtung: Expertenbegutachtung
 Identifikatoren: DOI: 10.1080/00268976.2012.663941
 Art des Abschluß: -

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Titel: Molecular Physics
Genre der Quelle: Zeitschrift
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Ort, Verlag, Ausgabe: London : Taylor & Francis
Seiten: - Band / Heft: 110 (15-16) Artikelnummer: - Start- / Endseite: 1627 - 1635 Identifikator: ISSN: 0026-8976
CoNE: https://pure.mpg.de/cone/journals/resource/954925264211