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  Vibrational enhancement of electron emission in CO (a(3)Pi) quenching at a clean metal surface.

Grätz, F., Engelhardt, D. P., Wagner, R. J. V., Haak, H., Meijer, G., Wodtke, A. M., et al. (2013). Vibrational enhancement of electron emission in CO (a(3)Pi) quenching at a clean metal surface. Physical Chemistry Chemical Physics, 15(36), 14951-14955. doi:10.1039/c3cp52468j.

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Grätz, F., Author
Engelhardt, D. P., Author
Wagner, R. J. V., Author
Haak, H., Author
Meijer, G., Author
Wodtke, A. M.1, Author           
Schäfer, T.1, Author           
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1Department of Dynamics at Surfaces, MPI for biophysical chemistry, Max Planck Society, ou_578600              

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 Abstract: We have combined a Stark decelerator with a molecular beam-surface scattering setup to accurately measure the absolute electron emission yield, gamma, of CO (a(3)Pi) quenching at a Au(111) surface with quantum state resolution. We clearly observe an enhanced probability of electron emission when scattering vibrationally excited states of CO from the surface.

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Language(s): eng - English
 Dates: 2013-07-192013
 Publication Status: Issued
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 Rev. Type: Peer
 Identifiers: DOI: 10.1039/c3cp52468j
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Title: Physical Chemistry Chemical Physics
Source Genre: Journal
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Pages: - Volume / Issue: 15 (36) Sequence Number: - Start / End Page: 14951 - 14955 Identifier: -