English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
 
 
DownloadE-Mail
 Local TagsRelease HistoryDetailsSummary
  Conversion of a singlet silylene to a stable biradical.

Mondal, K. C., Roesky, H. W., Schwarzer, M. C., Frenking, G., Tkach, I., Wolf, H., et al. (2013). Conversion of a singlet silylene to a stable biradical. Angewandte Chemie International Edition, 52(6), 1801-1805. doi:10.1002/anie.201204487.

Item is

 

show all hide all

Basic

show hide
Item Permalink: https://hdl.handle.net/11858/00-001M-0000-000E-802F-B Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0027-C85B-D
Genre: Journal Article

Files

show Files
hide Files
:
1629157.pdf (Publisher version), 484KB
 
File Permalink:
-
Name:
1629157.pdf
Description:
-
OA-Status:
Visibility:
Restricted (UNKNOWN id 303; )
MIME-Type / Checksum:
application/pdf
Technical Metadata:
Copyright Date:
-
Copyright Info:
-
License:
-
:
1629157-Suppl.pdf (Supplementary material), 4MB
View   Save
File Permalink:
https://hdl.handle.net/11858/00-001M-0000-000E-8036-A
Name:
1629157-Suppl.pdf
Description:
-
OA-Status:
Visibility:
Public
MIME-Type / Checksum:
application/pdf / [MD5]
Technical Metadata:
View
Copyright Date:
-
Copyright Info:
-
License:
-

Locators

show
hide
Locator:
http://onlinelibrary.wiley.com/doi/10.1002/anie.201204487/pdf (Publisher version)
Description:
-
OA-Status:

Creators

show
hide
 Creators:
Mondal, K. C., Author
Roesky, H. W., Author
Schwarzer, M. C., Author
Frenking, G., Author
Tkach, I.1, Author           
Wolf, H., Author
Kratzert, D., Author
Herbst-Irmer, R., Author
Niepçtter, B., Author
Stalke, D., Author
Affiliations:
1Research Group of Electron Paramagnetic Resonance, MPI for biophysical chemistry, Max Planck Society, ou_578606              

Content

show
hide
Free keywords: -
 Abstract: Silicon becomes colored: Stable biradicals were prepared from an N-heterocyclic carbene stabilized SiCl2 and a cyclic alkyl(amino)carbene, and characterized as two polymorphs. The deep-blue crystals of one polymorph are stable upon exposure to air for about a week, while the solution in THF decomposes rapidly when exposed to air. In a side reaction, the different carbene species react with each other under C[BOND]H activation and C[BOND]C bond formation in the presence of the biradical.

Details

show
hide
Language(s): eng - English
 Dates: 2012-12-202013-02-04
 Publication Status: Issued
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201204487
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Angewandte Chemie International Edition
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: -
Pages: - Volume / Issue: 52 (6) Sequence Number: - Start / End Page: 1801 - 1805 Identifier: ISSN: 0570-0833