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  Porphyrin-cyclophanes with 7,7,8,8-tetracyanoquinodimethane as an especially strong electron-acceptor: syntheses, properties, electron-transfer interactions

Staab, H. A., Weikard, J., Rückermann, A., & Schwögler, A. (1998). Porphyrin-cyclophanes with 7,7,8,8-tetracyanoquinodimethane as an especially strong electron-acceptor: syntheses, properties, electron-transfer interactions. European Journal of Organic Chemistry, 1998(12), 2703-2711. doi:10.1002/(SICI)1099-0690(199812)1998:12<2703:AID-EJOC2703>3.0.CO;2-I.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-002B-343E-C Version Permalink: https://hdl.handle.net/11858/00-001M-0000-002B-3445-9
Genre: Journal Article
Alternative Title : Porphyrin-cyclophanes with 7,7,8,8-tetracyanoquinodimethane as an especially strong electron-acceptor: syntheses, properties, electron-transfer interactions

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EurJOrgChem_1998_2703.pdf (Any fulltext), 180KB
 
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 Creators:
Staab, Heinz A.1, Author           
Weikard, Jan1, Author           
Rückermann, Andreas1, Author           
Schwögler, Anja1, Author           
Affiliations:
1Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society, ou_1497706              

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Free keywords: Porphyrin-acceptor cyclophanes / 7,7,8,8-Tetracyanoquinodimethane (TCNQ)-bridged porphyrins / Electrontransfer- related properties
 Abstract: Previous work on intramolecular electron-transfer compounds of the quinone-porphyrin cyclophane type with gradually increasing electron-acceptor strength was now extended to acceptor-porphyrin cyclophanes with 7,7,8,8-tetracyanoquinodimethane (TCNQ) as an especially strong electron-acceptor. The vertically stacked TCNQ-porphyrin cyclophane 1 was prepared in a multi-step synthesis. Physical properties related to structure and electron-transfer processes of 1 are reported. To determine the distance dependence of the interaction between the electron-acceptor TCNQ and the porphyrin, first results on the synthesis of the corresponding naphthalene-spacered TCNQ-porphyrin cyclophane 15 are presented.

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Language(s): eng - English
 Dates: 1998-06-251998-12-23
 Publication Status: Issued
 Pages: 10
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: eDoc: 666235
DOI: 10.1002/(SICI)1099-0690(199812)1998:12<2703::AID-EJOC2703>3.0.CO;2-I
URI: http://onlinelibrary.wiley.com/doi/10.1002/(SICI)1099-0690(199812)1998:12%3C2703::AID-EJOC2703%3E3.0.CO;2-I/abstract
URI: http://onlinelibrary.wiley.com/doi/10.1002/(SICI)1099-0690(199812)1998:12%3C2703::AID-EJOC2703%3E3.0.CO;2-I/full
Other: 4906
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Title: European Journal of Organic Chemistry
  Other : Eur. J. Org. Chem.
Source Genre: Journal
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Publ. Info: Weinheim, Germany : Wiley-VCH
Pages: - Volume / Issue: 1998 (12) Sequence Number: - Start / End Page: 2703 - 2711 Identifier: ISSN: 1434-193X
CoNE: https://pure.mpg.de/cone/journals/resource/954926953810