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  [C10N2H10][ZnCl(HPO4)]2: A New Templated Zincophosphate Containing Tetrahedral Nets with 63 Topology

Natarajan, S., Ewald, B., Prots, Y., & Kniep, R. (2005). [C10N2H10][ZnCl(HPO4)]2: A New Templated Zincophosphate Containing Tetrahedral Nets with 63 Topology. Zeitschrift für anorganische und allgemeine Chemie, 631(9), 1622-1626. doi:10.1002/zaac.200500062.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0015-2C7F-4 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0019-EAAA-7
Genre: Journal Article

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 Creators:
Natarajan, S.1, Author           
Ewald, B.1, Author           
Prots, Y.2, Author           
Kniep, R.3, Author           
Affiliations:
1Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863404              
2Yuri Prots, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863424              
3Rüdiger Kniep, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863437              

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 Abstract: The crystal structure of [C10N2H10][ZnCl(HPO4)]2 contains corrugated tetrahedral layers equation image with 63 topology. Charge balance is achieved by insertion of diprotonated 4,4′-bipyridine between the layers. Crystal data: monoclinic, P21/n (no. 14), a = 4.8832(2) Å, b = 22.673(2) Å, c = 8.1643(4) Å, β = 104.02(1)°; V = 877.0(1) Å3; Z = 4; R1 = 0.041 and wR2 = 0.088 for 1836 reflections [I > 2σ(I)]. Tetrahedral layers equation image are also observed in other organo-ammonium templated compounds. However, their topologies are characterized by 4.82 nets. With the title compound a layered tetrahedral net equation image with 63-topology is reported for the first time.

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Language(s): eng - English
 Dates: 2005-07-01
 Publication Status: Issued
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: -
 Identifiers: eDoc: 233604
DOI: 10.1002/zaac.200500062
 Degree: -

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Title: Zeitschrift für anorganische und allgemeine Chemie
  Other : Zeitschrift fuer Anorganische und Allgemeine Chemie
  Other : Journal of Inorganic and General Chemistry
  Other : J. Inorg. Gen Chem.
  Abbreviation : Z. Anorg. Allg. Chem.
Source Genre: Journal
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Publ. Info: Weinheim : WILEY-VCH Verlag GmbH & Co. KGaA
Pages: - Volume / Issue: 631 (9) Sequence Number: - Start / End Page: 1622 - 1626 Identifier: ISSN: 0044-2313
CoNE: https://pure.mpg.de/cone/journals/resource/954925453895