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キーワード:
Ammonolysis; Ceramics; Nitrides; Sol–gel processes
要旨:
The acid-catalyzed ammonolysis of the hitherto unknown compound tris(dimethylamino)silylamine (1), which is prepared from SiCl4 in high yield and purity, results in the preparation of a silicon diimide gel. The probable first step in this process is the acid-catalyzed self-condensation of 1 to the cyclic trimer [{(CH3)2N}2SiNH]3. This ammonolysis under mild conditions in THF provides a semirigid translucent gel. On drying under mild conditions in an ammonia atmosphere this non-oxide gel yields a high surface area silicon diimide xerogel that is the first example of a porous non-oxide silicate gel.
