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  [Cu2{1,4-bis[(3-methyl-2-pyridyl)amino]phthalazine-H}(N3)3] at 40K

Goeta, A. E., Thompson, L. K., Sheppard, C. L., Tandon, S. S., Lehmann, C. W., Cosier, J., et al. (1999). [Cu2{1,4-bis[(3-methyl-2-pyridyl)amino]phthalazine-H}(N3)3] at 40K. Acta Crystallographica, Section C: Crystal Structure Communications, 55(Part 8), 1243-1246. doi:10.1107/S0108270199005648.

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 Creators:
Goeta, Andres E.1, Author
Thompson, Laurence K.2, Author
Sheppard, Christopher L.2, Author
Tandon, Santokh S.2, Author
Lehmann, Christian W.1, Author              
Cosier, John3, Author
Webster, Craig3, Author
Howard, Judith A. K.1, Author
Affiliations:
1Department of Chemistry, University of Durham, South Road, Durham, DH1 3LE, UK, ou_persistent22              
2bDepartment of Chemistry, Memorial University of Newfoundland, St Johns, Newfoundland, Canada AIB 3X7, ou_persistent22              
3COxford Cryosystems, 3 Blenheim Office Park, Lower Road, Long Hanborough, Oxford OX8 8LN, England, ou_persistent22              

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 Abstract: The structure of the title compound, μ-azido-1:2κ2N1-[μ-4-(3-methyl-2-pyridyl-2κN-amino)-1-(3-methyl-2-pyridyl-1κN-imino)-1,2-dihydrophthalazin-2-yl-1:2κ2N2:N3]-bis[(azido-κN1)copper(II)], [Cu2(C20H17N6)(N3)3], (I), determined from data recorded at 40(1)K using a new open-flow He gas cryostat, is presented here as part of an extended study program on dicopper(II) azide-bridged compounds. Each pair of CuII centres in (I) is equatorially bridged by a μ2-1,1-azide, with a bridge angle of 107.2 (1)°. The dinuclear centres form tetranuclear clusters through two μ2-1,3-azide bridges, which in turn form chains along the a axis. Two C-H...N intermolecular interactions interlink these chains along the [110] and [11 ̅ 0] directions.

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Language(s): eng - English
 Dates: 1998-12-211999-04-211999-08-01
 Publication Status: Published in print
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1107/S0108270199005648
 Degree: -

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Title: Acta Crystallographica, Section C: Crystal Structure Communications
  Other : Acta Crystallogr., Sect. C: Cryst. Struct. Commun.
Source Genre: Journal
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Affiliations:
Publ. Info: Copenhagen, Denmark : Published for International Union of Crystallography by Munksgaard
Pages: - Volume / Issue: 55 (Part 8) Sequence Number: - Start / End Page: 1243 - 1246 Identifier: ISSN: 0108-2701
CoNE: https://pure.mpg.de/cone/journals/resource/110987085479123