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Free keywords:
p-Aminophenol; p-Nitrophenol; Catalytic activity; Hydrogenation; Mass
transport; Pt catalyst;
Abstract:
The hydrogenation of p-nitrophenol (PNP) to p-aminophenol (PAP) using NaBH4 as a reducing agent was studied as a test reaction for determining the catalytic activity of supported Pt catalysts. The initial reaction rate, which is accessible within less than 10minutes via online UV-vis spectroscopy at room temperature, ambient pressure and in water as a solvent, was used as measure for the catalytic activity. For three Pt catalysts supported on porous SiO2, porous glass and Al2O3, respectively, significant differences in the catalytic activity were observed. However, especially in case of very active catalysts, limitations of the reaction by internal or external mass transfer have to be considered.
