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Abstract:
The triangular lattice NaxRhO2 contains a 4d Rh element with large spin orbit coupling, and the electron-electron correlation effect is expected to have some novel physical properties. Here we report NaRhO2 crystal growth by Na2CO3 vapor growth and a series of NaxRhO2 (0.25 <= x <= 1) crystals prepared using the chemical desodiation method. NaxRhO2 reveals a layer structure with the space group R (3) over barm, and the lattice parameter a evolves from 3.09 to 3.03 angstrom and c from 15.54 to 15.62 angstrom when x decreases from 1.0 to 0.2. Decreasing potassium concentration leads to a contraction of the RhO6 octahedral layers, which may be attributed to a higher covalency of Rh-O bonds. More important, the metal-insulator transition in NaxRhO2 was observed in resistivity along the ab plane. The conducting mechanism of NaxRhO2 is strongly dependent on x. Two-dimensional variable range hopping (VRH) mechanisms (0.67 <= x <= 1) and metallic behaviors (0.42 and 0.47) are observed in temperature-dependent resistivity. The origin of this metal-insulator transition was discussed on the basis of the loffe-Regel criterion. Our work demonstrates the strong correlation between sodium concentration and physical properties of NaxRhO2.
