Deutsch
 
Hilfe Datenschutzhinweis Impressum
  DetailsucheBrowse

Datensatz

DATENSATZ AKTIONENEXPORT
 
 
DownloadE-Mail
 DetailsÜbersicht
  Electrospray mass spectrometry for detailed mechanistic studies of a complex organocatalyzed triple cascade reaction

Alachraf, M. W., Handayani, P. P., Hüttl, M. R. M., Grondal, C., Enders, D., & Schrader, W. (2011). Electrospray mass spectrometry for detailed mechanistic studies of a complex organocatalyzed triple cascade reaction. Organic & Biomolecular Chemistry, 9(4), 1047-1053. doi:10.1039/C003433A.

Item is

 

einblenden: alle ausblenden: alle

Basisdaten

einblenden: ausblenden:
Datensatz-Permalink: https://hdl.handle.net/11858/00-001M-0000-0014-C9CE-F Versions-Permalink: https://hdl.handle.net/11858/00-001M-0000-0014-C9CF-D
Genre: Zeitschriftenartikel

Externe Referenzen

einblenden:

Urheber

einblenden:
ausblenden:
 Urheber:
Alachraf, Mohammed Wasim1, Autor           
Handayani, Peni Purwa1, Autor           
Hüttl, Matthias R. M.2, Autor
Grondal, Christoph2, Autor
Enders, Dieter2, Autor
Schrader, Wolfgang1, Autor           
Affiliations:
1Service Department Schrader (MS), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445629              
2Institut für Organische Chemie, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany, ou_persistent22              

Inhalt

einblenden:
ausblenden:
Schlagwörter: -
 Zusammenfassung: The development of modular combinations of organocatalytic reactions into cascades has been shown to be an effective tool despite the fact that the mechanism of such a complex organocatalytic multistep cascade reaction still remains poorly understood. Here the detailed mechanistic studies of a complex organocatalytic triple cascade reaction for the synthesis of tetra-substituted cyclohexene carbaldehydes are reported. The investigation has been carried out using a triple quadrupole mass spectrometer with electrospray ionization. Important intermediates were detected and characterized through MS/MS studies. A detailed formation pathway is presented based on these characterized intermediates, and supporting the proposed mechanism of the formation of the substituted cyclohexene carbaldehydes.

Details

einblenden:
ausblenden:
Sprache(n): eng - English
 Datum: 2010-02-232010-10-212010-12-132011-02-21
 Publikationsstatus: Erschienen
 Seiten: 7
 Ort, Verlag, Ausgabe: -
 Inhaltsverzeichnis: -
 Art der Begutachtung: Expertenbegutachtung
 Identifikatoren: DOI: 10.1039/C003433A
 Art des Abschluß: -

Veranstaltung

einblenden:

Entscheidung

einblenden:

Projektinformation

einblenden:

Quelle 1

einblenden:
ausblenden:
Titel: Organic & Biomolecular Chemistry
  Andere : Organic and Biomolecular Chemistry
  Kurztitel : Org. Biomol. Chem.
Genre der Quelle: Zeitschrift
 Urheber:
Affiliations:
Ort, Verlag, Ausgabe: Cambridge : Royal Society of Chemistry
Seiten: 7 Band / Heft: 9 (4) Artikelnummer: - Start- / Endseite: 1047 - 1053 Identifikator: ISSN: 1477-0520
CoNE: https://pure.mpg.de/cone/journals/resource/954925269322