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  Sublimable Single Ion Magnets Based on Lanthanoid Quinolinate Complexes: The Role of Intermolecular Interactions on Their Thermal Stability

Cañon-Mancisidor, W., Miralles, S. G., Baldovi, J., Espallargas, G. M., Gaita-Ariño, A., & Coronado, E. (2018). Sublimable Single Ion Magnets Based on Lanthanoid Quinolinate Complexes: The Role of Intermolecular Interactions on Their Thermal Stability. Inorganic Chemistry, 57(22), 14170-14177. doi:10.1021/acs.inorgchem.8b02080.

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Item Permalink: https://hdl.handle.net/21.11116/0000-0002-6B42-C Version Permalink: https://hdl.handle.net/21.11116/0000-0002-A441-B
Genre: Journal Article

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A detailed explanation of the synthesis, experimental, compound characterization, FTIR, thermal properties, PXRD, SXRD, dc magnetic susceptibility, ac magnetic susceptibility, film fabrication, film characterization, and magnetic properties of the film
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https://dx.doi.org/10.1021/acs.inorgchem.8b02080 (Publisher version)
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 Creators:
Cañon-Mancisidor, W.1, 2, 3, Author
Miralles, S. G.1, Author
Baldovi, J.4, Author           
Espallargas, G. M.1, Author
Gaita-Ariño, A.1, Author
Coronado, E.1, Author
Affiliations:
1Instituto de Ciencia Molecular (ICMol), Universitat de València, ou_persistent22              
2Facultad de Química y Biología, Depto. de Química de los Materiales, Universidad de Santiago de Chile, ou_persistent22              
3Center for the Development of Nanoscience and Nanotechnology, CEDENNA, ou_persistent22              
4Theory Group, Theory Department, Max Planck Institute for the Structure and Dynamics of Matter, Max Planck Society, ou_2266715              

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 Abstract: We report the design, preparation, and characterization of two families of thermally robust coordination complexes based on lanthanoid quinolinate compounds: [Ln(5,7-Br2q)4]− and [Ln(5,7-ClIq)4]−, where q = 8-hydroquinolinate anion and Ln = DyIII, TbIII, ErIII, and HoIII. The sodium salt of [Dy(5,7-Br2q)4]− decomposes upon sublimation, whereas the sodium salt of [Dy(5,7-ClIq)4]−, which displays subtly different crystalline interactions, is sublimable under gentle conditions. The resulting film presents low roughness with high coverage, and the molecular integrity of the coordination complex is verified through AFM, MALDI-TOF, FT-IR, and microanalysis. Crucially, the single-molecule magnet behavior exhibited by [Dy(5,7-ClIq)4]− in bulk remains detectable by ac magnetometry in the sublimated film.

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Language(s): eng - English
 Dates: 2018-07-252018-10-312018-11-19
 Publication Status: Issued
 Pages: 8
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1021/acs.inorgchem.8b02080
 Degree: -

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Project name : The present work has been funded by the EU (COST action MOLSPIN 15128, ERC Consolidator Grant DECRESIM 647301, and Project COSMICS 66726), the Spanish MINECO (grant MAT2017-89993-R, CTQ2014-52758-P, CTQ2014-59209-P and “ Unidad de Excelencia Mar ı ́ ade Maeztu ” MDM-2015-0538 granted to ICMol), and the Generalitat Valenciana (Prometeo Program of excellence). A.G.-A. and G.M.E acknowledge funding by the MINECO (Ramo ́ n y Cajal contracts). J.J.B. thanks the EU for for a Marie Curie Fellowship (H2020-MSCA-IF-2016-751047). S.G.M. thanks the Spanish MINECO for a FPI predoctoral grant. W.C.-M. thanks FONDECYT de Iniciacio ́ n 11160830 for fi nancial support and Redes Internacionales para Investiga- dores en Etapa Inicial, REDI170277. MALDI-TOF was performed in the Proteomics Unit of SCSIE University of Valencia that belongs to ProteoRed, PRB2-ISCIII, supported by grant PT13/0001.
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Title: Inorganic Chemistry
  Abbreviation : Inorg. Chem.
Source Genre: Journal
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Publ. Info: Washington, DC : American Chemical Society
Pages: 8 Volume / Issue: 57 (22) Sequence Number: - Start / End Page: 14170 - 14177 Identifier: ISSN: 0020-1669
CoNE: https://pure.mpg.de/cone/journals/resource/0020-1669