A chemo- and stereoselective reduction of cycloalkynes to (E)- cycloalkenes

Fürstner, A.; Radkowski, K.

doi:10.1039/B207169J

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A chemo- and stereoselective reduction of cycloalkynes to (E)- cycloalkenes

Fürstner, A., & Radkowski, K. (2002). A chemo- and stereoselective reduction of cycloalkynes to (E)- cycloalkenes. Chemical Communications, (18), 2182-2183. doi:10.1039/B207169J.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-000F-9A45-8 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-001A-2AA6-A

Genre: Journal Article

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Creators:
Fürstner, A.¹, Author
Radkowski, K.¹, Author

Affiliations:
1Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445584

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Abstract: A stereoselective entry into (E)-cycloalkenes is described, comprising the ring closing alkyne metathesis (RCAM) of suitable diynes, a ruthenium-catalyzed trans-selective hydrosilylation of the cycloalkynes thus formed, followed by a desilylation of the resulting vinylsilanes mediated by AgF.

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Language(s): eng - English

Dates: Date issued: 2002

Publication Status: Issued

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Rev. Type: Peer

Identifiers: eDoc: 19903
DOI: 10.1039/B207169J
ISI: 000177996600092

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Title: Chemical Communications

Alternative Title : Chem. Commun.

Source Genre: Journal

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Pages: - Volume / Issue: (18) Sequence Number: - Start / End Page: 2182 - 2183 Identifier: ISSN: 1359-7345