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  A Fully Delocalized Mixed‐Valence Bis‐μ(Thiolato) Dicopper Complex: A Structural and Functional Model of the Biological CuA Center

Gennari, M., Pécaut, J., DeBeer, S., Neese, F., Collomb, M.-N., & Duboc, C. (2011). A Fully Delocalized Mixed‐Valence Bis‐μ(Thiolato) Dicopper Complex: A Structural and Functional Model of the Biological CuA Center. Angewandte Chemie International Edition, 50(25), 5662-5666. doi:10.1002/anie.201100605.

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Item Permalink: https://hdl.handle.net/21.11116/0000-0007-FF38-C Version Permalink: https://hdl.handle.net/21.11116/0000-0007-FF39-B
Genre: Journal Article

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 Creators:
Gennari, Marcello1, Author
Pécaut, Jacques2, Author
DeBeer, Serena3, Author
Neese, Frank4, 5, Author           
Collomb, Marie-Noelle1, Author
Duboc, Carole1, Author
Affiliations:
1Université Joseph Fourier Grenoble 1/CNRS, Département de Chimie Moléculaire, UMR‐5250, Laboratoire de Chimie Inorganique Redox, Institut de Chimie Moléculaire de Grenoble FR‐CNRS‐2607, BP‐53, 38041 Grenoble Cedex 9 (France), ou_persistent22              
2Laboratoire de Reconnaissance Ionique et Chimie de Coordination, Service de Chimie Inorganique et Biologique (UMR E‐3 CEA/UJF, FRE3200 CNRS), CEA‐Grenoble, INAC, 17 rue des Martyrs 38054 Grenoble cedex 9 (France), ou_persistent22              
3Department of Chemistry and Chemical Biology, Cornell University, Ithaca, NY 14853 (USA), ou_persistent22              
4Lehrstuhl für Theoretische Chemie, Institut für Physikalische und Theoretische Chemie, Universität Bonn, Wegelerstrasse 12, D-53115 Bonn, Germany, ou_persistent22              
5Max‐Planck‐Institut für Bioanorganische Chemie, Stiftstrasse 34‐36, 45470 Mülheim an der Ruhr (Germany), ou_persistent22              

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 Abstract: A {Cu2S2} diamond core has been stabilized thanks to the synthesis of a novel dinucleating ligand. The resulting dicopper complex has been isolated in the two formal oxidation states (see picture) that mimic most of the essential structural, spectroscopic, and functional properties of the CuA center.

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Language(s): eng - English
 Dates: 2011-05-092011-06-14
 Publication Status: Issued
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201100605
 Degree: -

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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem., Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 50 (25) Sequence Number: - Start / End Page: 5662 - 5666 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851