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  Short synthesis of labeled and unlabeled 6Z,9Z,12Z,15-hexadecatetraenoic acid as metabolic probes for biosynthetic studies on diatoms

Pohnert, G., Adolph, S., & Wichard, T. (2004). Short synthesis of labeled and unlabeled 6Z,9Z,12Z,15-hexadecatetraenoic acid as metabolic probes for biosynthetic studies on diatoms. Chemistry and Physics of Lipids, 131(2), 159-166. doi:10.1016/j.chemphyslip.2004.04.011.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0012-A2C3-C Version Permalink: https://hdl.handle.net/21.11116/0000-0005-BB29-B
Genre: Journal Article

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 Creators:
Pohnert, G.1, Author           
Adolph, S.1, Author           
Wichard, T.1, 2, Author           
Affiliations:
1Department of Bioorganic Chemistry, MPI for Chemical Ecology, Max Planck Society, ou_24028              
2IMPRS on Ecological Interactions, MPI for Chemical Ecology, Max Planck Society, Jena, DE, ou_421900              

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Free keywords: One-pot synthesis Bis-wittig reaction Homoconjugated tetraenes Deuterium labeled Unsaturated fatty acids Reductive olefination. Polyunsaturated fatty-acids Activated chemical defense Thalassiosira-rotula Copepod reproduction Skeletonema-costatum Wittig approach Aldehydes Algae. Biochemistry & Biophysics in Current Contents(R)/Life Sciences.
 Abstract: We describe a short synthesis of the unusual polyunsaturated 6Z,9Z, 12Z, 15-hexadecatetraenoic acid found in marine and fresh water diatoms. Using a one pot reductive bis-Wittig-olefination, the homoconjugated tetraene backbone of the fatty acid can be

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 Dates: 2004
 Publication Status: Issued
 Pages: -
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 Rev. Type: -
 Identifiers: Other: BOL183
DOI: 10.1016/j.chemphyslip.2004.04.011
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Title: Chemistry and Physics of Lipids
  Other : Chem. Phys. Lipids
Source Genre: Journal
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Publ. Info: Amsterdam : Elsevier
Pages: - Volume / Issue: 131 (2) Sequence Number: - Start / End Page: 159 - 166 Identifier: ISSN: 0009-3084
CoNE: https://pure.mpg.de/cone/journals/resource/954925390252