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  Higher Alcohol Synthesis Over Rh Catalysts: Conditioning of Rh/N-CNTs by Co and Mn Entrapped in the Support

Xie, Z., Frank, B., Huang, X., Schlögl, R., & Trunschke, A. (2016). Higher Alcohol Synthesis Over Rh Catalysts: Conditioning of Rh/N-CNTs by Co and Mn Entrapped in the Support. Catalysis Letters, 146(12), 2417-2424. doi: 10.1007/s10562-016-1875-6.

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 Creators:
Xie, Zailai1, 2, Author           
Frank, Benjamin1, 3, Author           
Huang, Xing1, Author           
Schlögl, Robert1, Author           
Trunschke, Annette1, Author           
Affiliations:
1Inorganic Chemistry, Fritz Haber Institute, Max Planck Society, ou_24023              
2College of Chemsitry, Fuzhou University, Qishan Campus, 2 Xueyuan Road, 350116 Fuzhou, People’s Republic of China, ou_persistent22              
3BasCat - UniCat BASF JointLab, Technische Universität Berlin, Sekr. EW K 01 , Hardenbergstr. 36, 10623 Berlin, Germany, ou_persistent22              

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 Abstract: Rh nanoparticles supported on commercial non-purified N-doped CNTs (NCNTs) containing residual CNT growth catalyst have been studied in hydrogenation of CO to higher alcohols. It has been found that Co and Mn residues in NCNTs are not inert, but change the catalyst under reaction conditions and efficiently promote the catalyst resulting in both increasing activity and selectivity to C2+ alcohols with time on stream.

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 Dates: 2016-07-042016-09-262016-10-132016-12
 Publication Status: Issued
 Pages: 8
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1007/s10562-016-1875-6
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Title: Catalysis Letters
Source Genre: Journal
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Publ. Info: New York : Springer
Pages: 8 Volume / Issue: 146 (12) Sequence Number: - Start / End Page: 2417 - 2424 Identifier: ISSN: 1011-372X
CoNE: https://pure.mpg.de/cone/journals/resource/954925586300