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  Incorporation of fluoroacetate into an aromatic polyketide and its influence on the mode of cyclization

Hong, H., Spiteller, D., & Spencer, J. B. (2008). Incorporation of fluoroacetate into an aromatic polyketide and its influence on the mode of cyclization. Angewandte Chemie, International Edition, 47(32), 6028-6032. doi:10.1002/anie.200801100.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0012-A0D5-3 Version Permalink: https://hdl.handle.net/21.11116/0000-0005-3BF0-A
Genre: Journal Article

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BOL457s1.pdf (Supplementary material), 76KB
 
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Hong, H., Author
Spiteller, D.1, Author           
Spencer, J. B., Author
Affiliations:
1Department of Bioorganic Chemistry, MPI for Chemical Ecology, Max Planck Society, ou_24028              

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 Abstract: Fluorine, changing course: Challenging the actinorhodin minimal polyketide synthase (act‐minimal PKS) with fluoroacetyl‐CoA as a starter unit yielded a fluorinated octaketide intermediate that led to the selective formation of fluoro‐SEK4b (see scheme); no fluoro‐SEK4 was formed(not shown).

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 Dates: 2008
 Publication Status: Issued
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 Identifiers: Other: BOL457
DOI: 10.1002/anie.200801100
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Title: Angewandte Chemie, International Edition
  Abbreviation : Angew. Chem., Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 47 (32) Sequence Number: - Start / End Page: 6028 - 6032 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851