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  Growth of pyromellitic dianhydride on an amino-terminated surface

Gölzhäuser, A., Panov, S., Mast, M., Schertel, A., Grunze, M., & Wöll, C. (1995). Growth of pyromellitic dianhydride on an amino-terminated surface. Surface Science, 334(1-3), 235-247. doi:10.1016/0039-6028(95)00251-0.

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Item Permalink: https://hdl.handle.net/21.11116/0000-0001-A93C-E Version Permalink: https://hdl.handle.net/21.11116/0000-0001-A93D-D
Genre: Journal Article

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SurfaceSci_334_1995_235.pdf (Any fulltext), 867KB
 
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Gölzhäuser, A., Author
Panov, S., Author
Mast, M., Author
Schertel, A., Author
Grunze, M.1, Author           
Wöll, Ch., Author
Affiliations:
1Cellular Biophysics, Max Planck Institute for Medical Research, Max Planck Society, ou_2364731              

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 Abstract: A novel strategy with regard to an improvement of polymer/metal adhesion is described and tested for the case of polyimide and copper. Pyromellitic dianhydride (PMDA) has been deposited on an amino-terminated surface, which was prepared by chemical vapor deposition of 4,4′-diaminodiphenyldisulfide (DAPS) on Cu(100). Photoelectron spectroscopy (XPS) and near-edge X-ray absorption fine structure (NEXAFS) spectroscopy have been used to show that an oriented monolayer of PMDA grows on the amino-terminated surface by chemical epitaxy. Heating to 450 K induces an imidization reaction. Comparison to data for codeposited DAPS + PMDA multilayers reveals that this imidization reaction produces intact imide units. In case of the multilayer significant amounts of Cu atoms are found to diffuse into the polyimide.

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Language(s): eng - English
 Dates: 1995-02-221994-08-151995-02-221995-07-10
 Publication Status: Issued
 Pages: 13
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1016/0039-6028(95)00251-0
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Title: Surface Science
  Abbreviation : Surf. Sci.
Source Genre: Journal
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Publ. Info: Amsterdam : Elsevier
Pages: - Volume / Issue: 334 (1-3) Sequence Number: - Start / End Page: 235 - 247 Identifier: Other: 0039-6028
CoNE: https://pure.mpg.de/cone/journals/resource/0039-6028