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  Synthesis of a new ruthenate Ba26Ru12O57

Lee, J.-E., Burkhardt, U., & Komarek, A. C. (2020). Synthesis of a new ruthenate Ba26Ru12O57. Crystals, 10: 355, pp. 1-12. doi:10.3390/cryst10050355.

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 Urheber:
Lee, Jeong-Eun1, Autor           
Burkhardt, Ulrich2, Autor           
Komarek, Alexander Christoph3, Autor           
Affiliations:
1Physics of Correlated Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863445              
2Ulrich Burkhardt, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863422              
3Alexander Komarek, Physics of Correlated Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863446              

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Schlagwörter: Dimer, Floating zone technique, High oxidation state, Kagome, Ruthenate, Singe cyrstal growth
 Zusammenfassung: Single crystals of Ba26Ru12O57 were grown by the floating zone method. The crystal structure is formed by an alternating stacking of pseudo-hexagonal Ru single layers and double layers. The Ru ions within the double layers are dimerized (Ru2O9) whereas the Ru ions within the single layers arrange in a distorted Kagome lattice of trigonal bipyramidally coordinated RuO5 polyhedra. Additionally, this Kagome lattice is "decorated" with RuO6 octahedra that are situated in the central free spaces within this Kagome lattice. According to the composition, the oxidation state of most of the Ru ions should be formally close to 5+. © 2020 by the authors. Licensee MDPI, Basel, Switzerland.

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Sprache(n): eng - English
 Datum: 2020-04-302020-04-30
 Publikationsstatus: Erschienen
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 Ort, Verlag, Ausgabe: -
 Inhaltsverzeichnis: -
 Art der Begutachtung: -
 Identifikatoren: DOI: 10.3390/cryst10050355
 Art des Abschluß: -

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Titel: Crystals
Genre der Quelle: Zeitschrift
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Ort, Verlag, Ausgabe: Basel, Switzerland : MDPI AG
Seiten: - Band / Heft: 10 Artikelnummer: 355 Start- / Endseite: 1 - 12 Identifikator: ISSN: 2073-4352
CoNE: https://pure.mpg.de/cone/journals/resource/2073-4352