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  Ion-pairing effects on 1H NMR chemical shifts of cyclic conjugated carbanions

Vogler, H. (1985). Ion-pairing effects on 1H NMR chemical shifts of cyclic conjugated carbanions. Journal of Organometallic Chemistry, 293(2), 131-137. doi:10.1016/0022-328X(85)80281-3.

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JOrganometallicChemistry_293_1985_131.pdf (Any fulltext), 405KB
 
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Vogler, Helmut1, Author              
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1Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society, ou_1497706              

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 Abstract: The 1H NMR chemical shifts of the cyclic conjugated hydrocarbon carbanions: cyclopentadienyl, cyclooctatetraene, cyclononatetraenyl, benzyl and methylene-cyclooctatrienyl anions, have been studied by a semiempirical approach in which the alkali counter ions are explicitly taken into account. The importance of electrostatic and covalent interactions between the ions and the ion-pairing effects on the proton shifts are elucidated.

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Language(s): eng - English
 Dates: 1985-03-122001-04-101985-09-24
 Publication Status: Published in print
 Pages: 7
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1016/0022-328X(85)80281-3
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Title: Journal of Organometallic Chemistry
  Other : J. Organomet. Chem.
Source Genre: Journal
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Publ. Info: Amsterdam : Elsevier
Pages: - Volume / Issue: 293 (2) Sequence Number: - Start / End Page: 131 - 137 Identifier: ISSN: 0022-328X
CoNE: https://pure.mpg.de/cone/journals/resource/954925622228