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  Catalytic Asymmetric Thioacetalization of Aldehydes

Kim, J. H., Tap, A., Liu, L., & List, B. (2017). Catalytic Asymmetric Thioacetalization of Aldehydes. Synlett, 28(03), 333-336. doi:10.1055/s-0036-1588083.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-002D-46AB-A Version Permalink: https://hdl.handle.net/21.11116/0000-0008-539A-D
Genre: Journal Article

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 Creators:
Kim, Ji Hye1, Author           
Tap, Aurélien1, Author           
Liu, Luping1, Author           
List, Benjamin1, Author           
Affiliations:
1Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445585              

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Free keywords: thioacetals; imidodiphosphates; Brønsted acid catalysis
 Abstract: A catalytic enantioselective thioacetalization reaction has been developed. Various aldehydes react with unsymmetrical 1,3- or 1,2-dithiols to furnish chiral, enantioenriched thioacetals in excellent enantioselectivities upon treatment with a nitrated imidodiphosphoric acid catalyst. The transformation is assumed to proceed via a thionium ion intermediate.

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Language(s): eng - English
 Dates: 2016-09-052016-10-042016-10-252017-02-14
 Publication Status: Issued
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1055/s-0036-1588083
 Degree: -

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Title: Synlett
  Abbreviation : Synlett
Source Genre: Journal
 Creator(s):
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Publ. Info: Stuttgart : Georg Thieme Verlag
Pages: - Volume / Issue: 28 (03) Sequence Number: - Start / End Page: 333 - 336 Identifier: ISSN: 0936-5214
CoNE: https://pure.mpg.de/cone/journals/resource/954925570856