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  Solid−Liquid Phase Equilibria of N-Methylephedrine Enantiomers in Two Chiral Solvents

Kaemmerer, H., Tulashie, S. K., Lorenz, H., & Seidel-Morgenstern, A. (2010). Solid−Liquid Phase Equilibria of N-Methylephedrine Enantiomers in Two Chiral Solvents. Journal of Chemical and Engineering Data, 55(3), 1131-1136. doi:10.1021/je900572c.

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Kaemmerer, H.1, Autor           
Tulashie, S. K.1, Autor           
Lorenz, H.2, Autor           
Seidel-Morgenstern, A.1, 2, Autor           
Affiliations:
1Otto-von-Guericke-Universität Magdeburg, External Organizations, ou_1738156              
2Physical and Chemical Foundations of Process Engineering, Max Planck Institute for Dynamics of Complex Technical Systems, Max Planck Society, ou_1738150              

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 Zusammenfassung: The ternary solubility phase diagrams of the N-methylephedrine species in two chiral solvents, (S)-ethyl lactate and (2R,3R)-diethyl tartrate, have been studied. Solubility measurements were performed for enantiomeric compositions and temperatures ranging from 1:1 mixtures to the pure enantiomer and from (273 to 313) K. Predicted ideal solubility curves of the N-methylephedrine species in both solvents revealed deviations from experimental data. The nonrandom two-liquid model was applied to quantify and parametrize these nonidealities and nonideal heterochiral interactions among the enantiomers by means of corresponding activity coefficients. The solvent−solute interactions were interpreted as nonchiral specific, since no asymmetry in the chiral systems were found. The selection of an appropriate solvent for a crystallization-based enantioseparation based on the shape of solubility isotherms is discussed. Copyright © 2009 American Chemical Society. [accessed November 26, 2009]

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Sprache(n): eng - English
 Datum: 2010
 Publikationsstatus: Erschienen
 Seiten: -
 Ort, Verlag, Ausgabe: -
 Inhaltsverzeichnis: -
 Art der Begutachtung: Expertenbegutachtung
 Identifikatoren: eDoc: 432863
Anderer: 30/10
DOI: 10.1021/je900572c
 Art des Abschluß: -

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Titel: Journal of Chemical and Engineering Data
Genre der Quelle: Zeitschrift
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Ort, Verlag, Ausgabe: Washington : American Chemical Society
Seiten: - Band / Heft: 55 (3) Artikelnummer: - Start- / Endseite: 1131 - 1136 Identifikator: ISSN: 0021-9568
CoNE: https://pure.mpg.de/cone/journals/resource/991042728182784