Deutsch
 
Hilfe Datenschutzhinweis Impressum
  DetailsucheBrowse

Datensatz

 
 
DownloadE-Mail
  Quantification Studies in continuous-flow 13C Nuclear Magnetic Resonance Spectroscopy by Use of Immobilized Paramagnetic Relaxation Agents

Fischer, H., Seiler, M., Ertl, T., Eberhardinger, U., Bertagnolli, H., Schmitt-Willich, H., et al. (2003). Quantification Studies in continuous-flow 13C Nuclear Magnetic Resonance Spectroscopy by Use of Immobilized Paramagnetic Relaxation Agents. The Journal of Physical Chemistry B, 107(20), 4879-4886. doi:10.1021/jp021631d.

Item is

Basisdaten

einblenden: ausblenden:
Genre: Zeitschriftenartikel

Externe Referenzen

einblenden:
ausblenden:
externe Referenz:
https://pubs.acs.org/doi/pdf/10.1021/jp021631d (Verlagsversion)
Beschreibung:
-
OA-Status:

Urheber

einblenden:
ausblenden:
 Urheber:
Fischer, HH1, Autor           
Seiler, M, Autor
Ertl, TS, Autor
Eberhardinger , U, Autor
Bertagnolli, H, Autor
Schmitt-Willich, H, Autor
Albert, K, Autor
Affiliations:
1External Organizations, ou_persistent22              

Inhalt

einblenden:
ausblenden:
Schlagwörter: -
 Zusammenfassung: Different types of immobilized free radicals as well as immobilized paramagnetic gadolinium(III) complexes were synthesized and used as relaxation agents to shorten the spin-lattice relaxation times T1 of analytes in quantitative continuous-flow 13C nuclear magnetic resonance spectroscopy (NMR). The immobilized paramagnetic relaxation agents were characterized with electron paramagnetic resonance spectroscopy (EPR) and extended X-ray absorption fine structure spectroscopy (EXAFS). With these types of paramagnetic relaxation agents, it was possible to obtain a 4-fold increase in signal-to-noise ratio per unit time, and an almost quantitative NMR spectra in continuous-flow 13C NMR spectroscopy could be acquired with this method.

Details

einblenden:
ausblenden:
Sprache(n):
 Datum: 2003-04
 Publikationsstatus: Erschienen
 Seiten: -
 Ort, Verlag, Ausgabe: -
 Inhaltsverzeichnis: -
 Art der Begutachtung: -
 Identifikatoren: DOI: 10.1021/jp021631d
BibTex Citekey: 2194
 Art des Abschluß: -

Veranstaltung

einblenden:

Entscheidung

einblenden:

Projektinformation

einblenden:

Quelle 1

einblenden:
ausblenden:
Titel: The Journal of Physical Chemistry B
  Andere : J. Phys. Chem. B
Genre der Quelle: Zeitschrift
 Urheber:
Affiliations:
Ort, Verlag, Ausgabe: Washington, D.C. : American Chemical Society
Seiten: - Band / Heft: 107 (20) Artikelnummer: - Start- / Endseite: 4879 - 4886 Identifikator: ISSN: 1520-6106
CoNE: https://pure.mpg.de/cone/journals/resource/1000000000293370_1