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  ZnPd/ZnO Aerogels as Potential Catalytic Materials

Ziegler, C., Klosz, S., Borhardt, L., Oschatz, M., Kaskel, S., Friedrich, M., et al. (2016). ZnPd/ZnO Aerogels as Potential Catalytic Materials. Advanced Functional Materials, 26(7), 1014-1020. doi:10.1002/adfm.201503000.

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 Creators:
Ziegler, Christoph1, Author
Klosz, Stefan1, Author
Borhardt, Lars2, Author
Oschatz, Martin2, 3, Author
Kaskel, Stefan2, 4, Author
Friedrich, Matthias5, 6, Author           
Kriegel, René5, 7, Author
Keilhauer, Toni5, 7, Author
Armbrüster, Marc5, 7, 8, Author
Eychmüller, Alexander1, Author
Affiliations:
1Physical Chemistry, TU Dresden, Dresden, Germany, ou_persistent22              
2Inorganic Chemistry, TU Dresden, Dresden, Germany, ou_persistent22              
3Department of Chemistry, Group of Inorganic Chemistry and Catalysis, University of Utrecht, Universiteitsweg 99, 3584 CG Utrecht, The Netherlands, ou_persistent22              
4Max-Planck-Institut für Kohlenforschung, Max Planck Society, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr, DE, ou_1445580              
5Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863404              
6Inorganic Chemistry, Fritz Haber Institute, Max Planck Society, ou_24023              
7Faculty of Natural Sciences, Institute of Chemistry, Materials for Innovative Energy Concepts, Technische Universität Chemnitz, 09107 Chemnitz, Germany, ou_persistent22              
8Max Planck Institute for Chemical Physics of Solids, Max Planck Society, Nöthnitzer Straße 40, 01187 Dresden, DE, ou_1863404              

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 Abstract: Many different aerogel materials are known to be accessible via the controlled destabilization of the respective nanoparticle suspensions. Especially for applications in heterogeneous catalysis such materials with high specific surface areas are highly desirable. Here, a facile method to obtain a mixed ZnPd/ZnO aerogel via a reductive treatment of a preformed Pd/ZnO aerogel is presented. Different morphologies of the Pd/ZnO aerogels could be achieved by controlling the destabilization of the ZnO sol. All aerogels show a high CO2 selectivity of up to 96% and a very good activity in methanol steam reforming that delivers hydrogen, which is one of the most important fuels for future energy concepts. The method presented is promising for different transition metal/metal oxide systems and hence opens a path to a huge variety of materials.

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 Dates: 2015-10-192015-07-202015-12-212016-02-16
 Publication Status: Issued
 Pages: 7
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/adfm.201503000
 Degree: -

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Title: Advanced Functional Materials
  Other : Adv. Funct. Mater.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH Verlag GmbH
Pages: 7 Volume / Issue: 26 (7) Sequence Number: - Start / End Page: 1014 - 1020 Identifier: ISSN: 1616-301X
CoNE: https://pure.mpg.de/cone/journals/resource/954925596563