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  Interplay of Method Development and Mechanistic Studies – From Aerobic Oxidative Coupling to Radical Reactions via Alkenyl Peroxides

Klussmann, M., & Schweitzer-Chaput, B. (2016). Interplay of Method Development and Mechanistic Studies – From Aerobic Oxidative Coupling to Radical Reactions via Alkenyl Peroxides. Synlett, 27(02), 190-202. doi:10.1055/s-0035-1560706.

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 Creators:
Klussmann, Martin1, Author              
Schweitzer-Chaput, Bertrand1, Author              
Affiliations:
1Research Group Klußmann, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445608              

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Free keywords: homogeneous catalysis, green chemistry, oxygen, perox- ides, radicals, reaction mechanisms, C–H functionalization
 Abstract: This account summarizes how scientific advances were made in the authors’ research group by combining method development in organic synthesis with detailed mechanistic studies. The discovery of an unexpected autoxidative coupling reaction led, by virtue of an ever increased understanding of its mechanism, to a strategy for green C–H functionalization reactions, novel modes of radical generation, addition reactions of ketones to alkenes and new insights into an old reaction, the Baeyer–Villiger oxidation.

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Language(s): eng - English
 Dates: 2016
 Publication Status: Published in print
 Pages: 13
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1055/s-0035-1560706
 Degree: -

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Title: Synlett
  Other : Synlett
Source Genre: Journal
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Publ. Info: Stuttgart : Georg Thieme Verlag
Pages: - Volume / Issue: 27 (02) Sequence Number: - Start / End Page: 190 - 202 Identifier: CoNE: https://pure.mpg.de/cone/journals/resource/954925570856