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  Bimetallic iron-tin catalyst for N(2)to NH(3)and a silyldiazenido model intermediate

Dorantes, M. J., Moore, J. T., Bill, E., Mienert, B., & Lu, C. C. (2020). Bimetallic iron-tin catalyst for N(2)to NH(3)and a silyldiazenido model intermediate. Chemical Communications, 56(75), 11030-11033. doi:10.1039/d0cc04563b.

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Item Permalink: https://hdl.handle.net/21.11116/0000-0007-A486-8 Version Permalink: https://hdl.handle.net/21.11116/0000-0007-A487-7
Genre: Journal Article

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 Creators:
Dorantes, Michael J.1, Author
Moore, James T.1, Author
Bill, Eckhard2, Author           
Mienert, Bernd2, 3, Author           
Lu, Connie C.4, Author           
Affiliations:
1external, ou_persistent22              
2Research Department DeBeer, Max Planck Institute for Chemical Energy Conversion, Max Planck Society, ou_3023871              
3Research Department Neese, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_2541710              
4External Organizations, ou_persistent22              

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 Abstract: A tin-supported iron catalyst produces 5.9 turnovers of NH(3)from N-2, using [Ph2NH2]OTf as the acid and CoCp2* as the reductant. Two redox states of the Fe(N-2) adduct and an Fe silyldiazenido complex were characterized using X-ray crystallography along with NMR and Mossbauer spectroscopies. Density functional theory calculations reveal that the charge on the Sn center correlates strongly with both the polarization of the N(2)moiety and the charge on the distal N atom.

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Language(s): eng - English
 Dates: 2020
 Publication Status: Issued
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: ISI: 000571593700004
DOI: 10.1039/d0cc04563b
 Degree: -

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Title: Chemical Communications
  Other : Chem. Commun.
Source Genre: Journal
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Publ. Info: Cambridge, UK : Royal Society of Chemistry
Pages: - Volume / Issue: 56 (75) Sequence Number: - Start / End Page: 11030 - 11033 Identifier: ISSN: 1359-7345
CoNE: https://pure.mpg.de/cone/journals/resource/954928495413