Practical separation of alcohol-ester mixtures using Deep-Eutectic-Solvents

Maugeri, Zaira; Leitner, Walter; Hammer, M.

doi:10.1016/j.tetlet.2012.10.044

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Practical separation of alcohol-ester mixtures using Deep-Eutectic-Solvents

Maugeri, Z., Leitner, W., & Hammer, M. (2012). Practical separation of alcohol-ester mixtures using Deep-Eutectic-Solvents. TETRAHEDRON LETTERS, 53(51), 6968-6971. doi:10.1016/j.tetlet.2012.10.044.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-000E-F2B7-1 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0023-C2D4-E

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Maugeri, Zaira¹, Author
Leitner, Walter^{1, 2}, Author
Hammer, M.¹, Author

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1 Rhein Westfal TH Aachen, Inst Tech & Makromol Chem, D-52074 Aachen, Germany , ou_persistent22
2Service Department Leitner (Technical Labs), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445626

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Abstract: Deep-Eutectic-Solvents (DES) were assessed for the separation of alcohol-ester mixtures, for example those typically obtained from catalytic kinetic resolutions of racemic alcohols. DES can efficiently dissolve molecules containing hydrogen-bond-donors (alcohols), whereas esters remain as second phase. By using this concept, tedious separation chromatographic steps may be easily overcome with bio-based non-hazardous solvents. (C) 2012 Elsevier Ltd. All rights reserved.

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Dates: Date issued: 2012-12-19

Publication Status: Issued

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Rev. Type: Peer

Identifiers: DOI: 10.1016/j.tetlet.2012.10.044

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Title: TETRAHEDRON LETTERS

Source Genre: Journal

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Pages: - Volume / Issue: 53 (51) Sequence Number: - Start / End Page: 6968 - 6971 Identifier: -