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  Swelling of latex particles—towards a solution of the riddle

Tripathi, A., Wei, C., & Tauer, K. (2017). Swelling of latex particles—towards a solution of the riddle. Colloid and Polymer Science, 295(1), 189-196. doi:10.1007/s00396-016-3988-2.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-002C-25C5-6 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-002C-4E1A-B
Genre: Journal Article

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 Creators:
Tripathi, Amit1, Author           
Wei, Chunxiang1, Author           
Tauer, Klaus1, Author           
Affiliations:
1Klaus Tauer, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_1863320              

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Free keywords: Open Access
 Abstract: The assumption that during emulsion polymerization, the monomer molecules simply diffuse through the aqueous phase into the latex particles is a commonplace. However, there are experimental hints that this might not be that easy. Here, simulation results are discussed based on Fick’s diffusion laws regarding the swelling of latex particles. The results of quantitative application of these laws for swelling of latex particles allow the conclusion that the instantaneous replenishment of the consumed monomer during emulsion polymerization requires a close contact between the monomer and the polymer particles.

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 Dates: 2016-12-082017
 Publication Status: Issued
 Pages: -
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 Table of Contents: -
 Rev. Type: Peer
 Identifiers: Other: Tripathi2016
DOI: 10.1007/s00396-016-3988-2
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Title: Colloid and Polymer Science
  Other : Colloid Polym. Sci.
Source Genre: Journal
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Publ. Info: Heidelberg : Springer-Verlag Heidelberg
Pages: - Volume / Issue: 295 (1) Sequence Number: - Start / End Page: 189 - 196 Identifier: ISSN: 0303-402X