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  A trans-Selective Hydroboration of Internal Alkynes

Sundararaju, B., & Fürstner, A. (2013). A trans-Selective Hydroboration of Internal Alkynes. Angewandte Chemie International Edition, 52(52), 14050-14054. doi:10.1002/anie.201307584.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0014-F494-D Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0014-F495-B
Genre: Journal Article

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anie_201307584_sm_miscellaneous_information.pdf (Supplementary material), 4MB
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https://hdl.handle.net/11858/00-001M-0000-0014-F496-9
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anie_201307584_sm_miscellaneous_information.pdf
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Copyright Date:
2013
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Wiley-VCH 69451 Weinheim, Germany
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 Creators:
Sundararaju, Basker1, Author           
Fürstner, Alois1, Author           
Affiliations:
1Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445584              

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Free keywords: alkynes; hydroboration; pinacolboronates; ruthenium; trans addition
 Abstract: Violate the rule: The reigning stereochemical principle of hydroboration is the suprafacial delivery of hydrogen and boron to the same π-face of a given starting material. This fundamental rule of cis addition is now easily broken for internal alkynes with the help of [Cp*Ru(MeCN)3]PF6 (Cp*=η5-C5Me5) as the catalyst. The resulting trans-selective hydroboration opens a practical new entry into E-configured alkenylboron derivatives.

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Language(s): eng - English
 Dates: 2013-08-282013-10-312013-12-23
 Publication Status: Issued
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201307584
 Degree: -

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Title: Angewandte Chemie International Edition
  Other : Angewandte Chemie - International Edition
  Abbreviation : Angew. Chem. Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH Verlag GmbH & Co. KGaA
Pages: 5 Volume / Issue: 52 (52) Sequence Number: - Start / End Page: 14050 - 14054 Identifier: CoNE: https://pure.mpg.de/cone/journals/resource/201310171