English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
 
 
DownloadE-Mail
 Local TagsRelease HistoryDetailsSummary
  Real-time observation of intra- and intermolecular vibrational energy flow of selectively excited alkyl iodides in solution: The effect of chemical substitution

Assmann, J., Charvat, A., Schwarzer, D., Kappel, C., Luther, K., & Abel, B. (2002). Real-time observation of intra- and intermolecular vibrational energy flow of selectively excited alkyl iodides in solution: The effect of chemical substitution. Journal of Physical Chemistry A, 106(21), 5197-5201. Retrieved from http://pubs.acs.org/doi/pdfplus/10.1021/jp015552y.

Item is

 

show all hide all

Basic

show hide
Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0012-F3BB-C Version Permalink: https://hdl.handle.net/11858/00-001M-0000-002A-3954-5
Genre: Journal Article

Files

show Files
hide Files
:
17070.pdf (Publisher version), 0B
 
File Permalink:
-
Name:
17070.pdf
Description:
-
OA-Status:
Visibility:
Restricted (UNKNOWN id 303; )
MIME-Type / Checksum:
application/pdf
Technical Metadata:
Copyright Date:
-
Copyright Info:
-
License:
-

Locators

show

Creators

show
hide
 Creators:
Assmann, J.1, Author           
Charvat, A.1, Author           
Schwarzer, D.2, Author           
Kappel, C., Author
Luther, K.1, Author           
Abel, B.3, Author
Affiliations:
1Department of Spectroscopy and Photochemical Kinetics, MPI for biophysical chemistry, Max Planck Society, ou_578624              
2Research Group of Reaction Dynamics, MPI for biophysical chemistry, Max Planck Society, ou_578601              
3Max Planck Society, ou_persistent13              

Content

show
hide
Free keywords: -
 Abstract: Intramolecular vibrational energy redistribution (IVR) and intermolecular vibrational energy transfer (VET) of two alkyl iodides (CF3CH2I and CH3CH2-I) selectively excited in the two quanta overtone region of the CH stretch vibration (upsilon(CH) = 2) were measured in real time in solution. In this study, we have focused on the effect of chemical substitution on the mechanisms and time scales of IVR and VET of this family of molecules. With a simple model. we have obtained global IVR and VET rate coefficients for both molecules. The magnitude and the variation of the relaxation rates upon chemical substitution provide evidence for a survival of hierarchical IVR in these solvated molecules. which is governed by specific low-order intramolecular interactions and which can be rationalized with a simple low-order coupling model. At the same time, the general assumption that VET is simply dominated by the lowest- frequency modes in a molecule is not supported.

Details

show
hide
Language(s): eng - English
 Dates: 2002-05-30
 Publication Status: Issued
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: eDoc: 17070
URI: http://pubs.acs.org/doi/pdfplus/10.1021/jp015552y
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Journal of Physical Chemistry A
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: -
Pages: - Volume / Issue: 106 (21) Sequence Number: - Start / End Page: 5197 - 5201 Identifier: -