New scandium rhodium boride Sc4Rh17B12 with a framework structure: synthesis, 
crystal structure, and properties

Alekseeva, A. M.; Leithe-Jasper, A.; Prots, Yu.; Schnelle, W.; Grin, Yu.; Antipov, E. V.

doi:10.1007/s11172-008-0082-z

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New scandium rhodium boride Sc₄Rh₁₇B₁₂ with a framework structure: synthesis, crystal structure, and properties

Alekseeva, A. M., Leithe-Jasper, A., Prots, Y., Schnelle, W., Grin, Y., & Antipov, E. V. (2008). New scandium rhodium boride Sc₄Rh₁₇B₁₂ with a framework structure: synthesis, crystal structure, and properties. Russian Chemical Bulletin, 57(3), 532-540. doi:10.1007/s11172-008-0082-z.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0019-80AB-1 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0019-80AD-E

Genre: Journal Article

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Creators:
Alekseeva, A. M.¹, Author
Leithe-Jasper, A.², Author
Prots, Yu.³, Author
Schnelle, W.⁴, Author
Grin, Yu.⁵, Author
Antipov, E. V.⁶, Author

Affiliations:
1Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863404
2Andreas Leithe-Jasper, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863406
3Yuri Prots, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863424
4Walter Schnelle, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863441
5Juri Grin, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863413
6external, ou_persistent22

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Abstract: The new scandium rhodium boride Sc4Rh17B12 was synthesized by arc-melting of the elements followed by annealing in inert atmosphere. The crystal structure of Sc4Rh17B12 was solved using single crystal X-ray diffraction data. The structure can be described as a three-dimensional framework formed by trigonal prisms [BRh6] and [BRh5Sc] with isolated boron atoms inside the prisms and trigonal prisms [BRh5B] representing the coordination polyhedra of paired boron atoms. The temperature dependences of the magnetic Susceptibility and specific resistance of Sc4Rh17B12 revealed that the compound is a Pauli paramagnet and shows metal-like specific resistance.

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Dates: Date issued: 2008-03-03

Publication Status: Issued

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Identifiers: ISI: 000263566900012
DOI: 10.1007/s11172-008-0082-z

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Title: Russian Chemical Bulletin

Other : Russ. Chem. Bull.

Source Genre: Journal

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Publ. Info: New York : Consultants Bureau

Pages: - Volume / Issue: 57 (3) Sequence Number: - Start / End Page: 532 - 540 Identifier: ISSN: 1066-5285
CoNE: https://pure.mpg.de/cone/journals/resource/954925601692