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  Ambiphilicity of a mononuclear cobalt(III) superoxo complex

Chen, T.-Y., Ho, P.-H., Spyra, C.-J., Meyer, F., Bill, E., Ye, S., et al. (2020). Ambiphilicity of a mononuclear cobalt(III) superoxo complex. Chemical Communications, 56(94), 14821-14824. doi:10.1039/D0CC05337F.

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Item Permalink: https://hdl.handle.net/21.11116/0000-0007-AB03-5 Version Permalink: https://hdl.handle.net/21.11116/0000-0007-AB04-4
Genre: Journal Article

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 Creators:
Chen, Ting-Yi1, 2, Author
Ho, Po-Hsun1, Author
Spyra, Can-Jerome2, Author
Meyer, Franc2, Author
Bill, Eckhard3, Author           
Ye, Shengfa4, 5, Author           
Lee, Way-Zen1, 6, Author
Affiliations:
1Department of Chemistry, National Taiwan Normal University, Taipei 11677, Taiwan, ou_persistent22              
2Universität Göttingen, Institut für Anorganische Chemie, D-37077 Göttingen, Germany , ou_persistent22              
3Research Department DeBeer, Max Planck Institute for Chemical Energy Conversion, Max Planck Society, ou_3023871              
4State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China , ou_persistent22              
5Research Group Ye, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_2541708              
6Department of Medicinal and Applied Chemistry, Kaohsiung Medical University, Kaohsiung 807, Taiwan , ou_persistent22              

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 Abstract: Addition of HOTf to a mixture of CoIII(BDPP)(O2˙) (1, H2BDPP = 2,6-bis((2-(S)-diphenylhydroxylmethyl-1-pyrrolidinyl)methyl)pyridine) and Cp*2Fe produced H2O2 in high yield implying formation of CoIII(BDPP)(OOH) (3), and reaction of Sc(OTf)3 with the same mixture gave a peroxo-bridged CoIII/ScIII5. These findings demonstrate the ambiphilic property of CoIII-superoxo 1.

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Language(s): eng - English
 Dates: 2020-08-052020-10-152020-12-07
 Publication Status: Issued
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1039/D0CC05337F
 Degree: -

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Title: Chemical Communications
  Abbreviation : Chem. Commun.
Source Genre: Journal
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Publ. Info: Cambridge, UK : Royal Society of Chemistry
Pages: - Volume / Issue: 56 (94) Sequence Number: - Start / End Page: 14821 - 14824 Identifier: ISSN: 1359-7345
CoNE: https://pure.mpg.de/cone/journals/resource/954928495413