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  Femtosecond UV-pump mid-IR probe spectroscopy of the ultrafast photodissociation of azide radicals from an azidoiron(III) complex.

Vennekate, H., Schwarzer, D., Torres-Alacan, J., & Vöhringer, P. (2013). Femtosecond UV-pump mid-IR probe spectroscopy of the ultrafast photodissociation of azide radicals from an azidoiron(III) complex. EPJ Web of Conferences, 41: UNSP 05028. doi:10.1051/epjconf/20134105028.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0014-3A50-8 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0027-C752-7
Genre: Conference Paper

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1827416.pdf (Publisher version), 675KB
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http://www.epj-conferences.org/articles/epjconf/pdf/2013/02/epjconf_up2012_05028.pdf (Publisher version)
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 Creators:
Vennekate, H.1, Author           
Schwarzer, D.1, Author           
Torres-Alacan, J., Author
Vöhringer, P., Author
Affiliations:
1Research Group of Reaction Dynamics, MPI for biophysical chemistry, Max Planck Society, ou_578601              

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 Abstract: The ultrafast photolysis of the cation complex [(cyclam-ac)FeN3]+ is studied by femtosecond spectroscopy with ultraviolet excitation and mid-infrared probing. Immediately after UV absorption, the excited complex undergoes internal conversion and azide dissociation within 2 ps. The subsequent vibrational relaxation in the electronic ground state and geminate recombination of the fragments take place on time scales of 13 and 20 ps, respectively.

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Language(s): eng - English
 Dates: 2013-03-132013
 Publication Status: Issued
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 Rev. Type: Peer
 Identifiers: DOI: 10.1051/epjconf/20134105028
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Title: 18th International Conference on Ultrafast Phenomena
Place of Event: Lausanne, SWITZERLAND
Start-/End Date: 2013-07-08 - 2013-07-13

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Title: EPJ Web of Conferences
Source Genre: Journal
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Pages: - Volume / Issue: 41 Sequence Number: UNSP 05028 Start / End Page: - Identifier: -