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  Li4[FeN2]: A Nitridoferrate(II) with Anions Isosteric with CO2. A Defect Variant of the Li3N Type Structure

Gudat, A., Kniep, R., & Rabenau, A. (1991). Li4[FeN2]: A Nitridoferrate(II) with Anions Isosteric with CO2. A Defect Variant of the Li3N Type Structure. Angewandte Chemie International Edition, 30(2), 199-200. doi:10.1002/anie.199101991.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0019-B7E5-D Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0019-B7E6-B
Genre: Journal Article

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 Creators:
Gudat, Axel1, Author
Kniep, Rüdiger2, Author           
Rabenau, Albrecht1, Author
Affiliations:
1external, ou_persistent22              
2External Organizations, ou_persistent22              

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 Abstract: The continual place-changing of iron atoms in the mixed crystal phases of composition Li4Fe1.04N2, during which the slightly corrigated Li2N layers are maintained, leads in a topotactic reaction to the formation of Li4[FeN2]. This presumably metastable nitridoferrate(II) is one of the lesser known nitridoferrates. Li4[FeN2] crystallizes in a defect variant of the Li3N structure (Li2Fe0.5-square-0.5N), in which Li2N layers are bound by linearly coordinated Fe(II) centers.

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 Dates: 1991-02-03
 Publication Status: Issued
 Pages: -
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 Table of Contents: -
 Rev. Type: -
 Identifiers: ISI: A1991FF90800022
DOI: 10.1002/anie.199101991
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Title: Angewandte Chemie International Edition
  Other : Angewandte Chemie International Edition in English
  Other : Angewandte Chemie - International Edition
  Abbreviation : Angew. Chem. Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 30 (2) Sequence Number: - Start / End Page: 199 - 200 Identifier: Other: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/201310171