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  Structural Diversity of Metallosupramolecular Assemblies Based on the Bent Bridging Ligand 4,4′-Dithiodipyridine

Seidel, R. W., Goddard, R., & Oppel, I. M. (2013). Structural Diversity of Metallosupramolecular Assemblies Based on the Bent Bridging Ligand 4,4′-Dithiodipyridine. Polymers, 5(2), 527-575. doi:10.3390/polym5020527.

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 Creators:
Seidel, Rüdiger W.1, Author
Goddard, Richard2, Author           
Oppel, Iris M.3, Author
Affiliations:
1Lehrstuhl für Analytische Chemie, Ruhr-Universität Bochum, Universitätsstraße 150, Bochum 44780, Germany , ou_persistent22              
2Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625              
3Institut für Anorganische Chemie, Rheinisch-Westfälische Technische Hochschule Aachen, Landoltweg 1, Aachen 52074, Germany, ou_persistent22              

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Free keywords: self-assembly; metallamacrocycle; coordination polymer; crystal engineering; 4,4′-dithiodipyridine; 4,4′-dipyridyldisulfide
 Abstract: 4,4′-Dithiodipyridine (dtdp), also termed 4,4′-dipyridyldisulfide, is a bridging ligand of the 4,4′-bipyridine type. The introduction of the disulfide moiety inevitably leads to a relatively rigid angular structure, which exhibits axial chirality. More than 90 metal complexes containing the dtdp ligand have been crystallographically characterised until now. This review focuses on the preparation and structural diversity of discrete and polymeric metallosupramolecular assemblies constructed from dtdp as bridging ligands. These encompass metallamacrocycles with M2L2 topology and coordination polymers with periodicity in one or two dimensions. One-dimensional coordination polymers represent the vast majority of the metallosupramolecular structures obtained from dtdp. These include repeated rhomboids, zigzag, helical and arched chains among other types. In this contribution, we make an attempt to provide a comprehensive account of the structural data that are currently available for metallosupramolecular assemblies based on the bent bridging ligand dtdp.

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Language(s): eng - English
 Dates: 2013-04-302013-04-022013-05-032013-05-21
 Publication Status: Published online
 Pages: 49
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.3390/polym5020527
 Degree: -

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Title: Polymers
Source Genre: Journal
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Publ. Info: Basel, Switzerland : MDPI AG
Pages: 49 Volume / Issue: 5 (2) Sequence Number: - Start / End Page: 527 - 575 Identifier: ISSN: 2073-4360
CoNE: https://pure.mpg.de/cone/journals/resource/2073-4360