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  The effect of the sulfur-metal bonding on the structure of self-assembled monolayers

Zharnikov, M., Frey, S., Rong, H., Yang, Y.-J., Heister, K., Buck, M., et al. (2000). The effect of the sulfur-metal bonding on the structure of self-assembled monolayers. Physical Chemistry Chemical Physics, 2(15), 3359-3362. doi:10.1039/B004232N.

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Item Permalink: https://hdl.handle.net/21.11116/0000-0001-BBAF-8 Version Permalink: https://hdl.handle.net/21.11116/0000-0001-BBB0-5
Genre: Journal Article

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PhysChemChemPhys_2_2000_3359.pdf (Any fulltext), 183KB
 
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http://pubs.rsc.org/en/content/articlepdf/2000/cp/b004232n (Any fulltext)
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https://doi.org/10.1039/B004232N (Any fulltext)
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 Creators:
Zharnikov, M., Author
Frey, S., Author
Rong, H., Author
Yang, Y.-J., Author
Heister, K., Author
Buck, M., Author
Grunze, M.1, Author           
Affiliations:
1Cellular Biophysics, Max Planck Institute for Medical Research, Max Planck Society, ou_2364731              

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 Abstract: The equilibrium structure of alkanethiol monolayers self-assembled on metal substrates is determined by a delicate interplay of the intermolecular chain–chain and chemisorptive substrate–head group inter actions. To understand the role of the individual constituents of this interplay, we studied the structure of biphenyl and perfluoroalkyl terminated alkanethiol monolayers self-assembled on Au and Ag. The structural characteristics of the monolayers derived from NEXAFS, FTIRRAS and XPS measurements point to a decisive role of the directional substrate–head group interactions.

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Language(s): eng - English
 Dates: 2000-05-262000-06-202000-07-062000
 Publication Status: Issued
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1039/B004232N
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Title: Physical Chemistry Chemical Physics
  Abbreviation : Phys. Chem. Chem. Phys.
Source Genre: Journal
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Publ. Info: Cambridge, England : Royal Society of Chemistry
Pages: - Volume / Issue: 2 (15) Sequence Number: - Start / End Page: 3359 - 3362 Identifier: ISSN: 1463-9076
CoNE: https://pure.mpg.de/cone/journals/resource/954925272413_1