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  A stable Ni–B catalyst in hydrogen generation via NaBH4 hydrolysis

Lee, J. K., Ann, H.-h., Yi, Y., Lee, K. W., Uhm, S., & Lee, J. (2011). A stable Ni–B catalyst in hydrogen generation via NaBH4 hydrolysis. Catalysis Communications, 16(1), 120-123. doi:10.1016/j.catcom.2011.09.015.

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 Creators:
Lee, Jae Kwang1, Author
Ann, Hyang-hwa1, 2, Author
Yi, Youngmi3, Author           
Lee, Kyu Wan2, Author
Uhm, Sunghyun1, Author
Lee, Jaeyoung1, 4, Author           
Affiliations:
1GIST, Ertl Ctr Electrochem & Catalysis, Kwangju, South Korea, ou_persistent22              
2School of Biological and Chemical Engineering, Yanbian University of Science and Technology, Yanji, Jilin 133000, China, ou_persistent22              
3Inorganic Chemistry, Fritz Haber Institute, Max Planck Society, ou_24023              
4Physical Chemistry, Fritz Haber Institute, Max Planck Society, ou_634546              

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Free keywords: Catalytic stability; Ni–B catalyst; Porous Ni support; Hydrogen generation; NaBH4
 Abstract: We provided a more stable and physically adhesive Ni–B catalyst onto a porous Ni support via a simple dipping- chemical reduction process without additional heat treatment. The morphology and the crystalline of the catalyst were found to be strongly dependent on the concentrations of Ni precursor and reductant. A steady-state production rate of hydrogen from NaBH4 is observed in the absence of mass loss of Ni–B catalyst and the activation energy of Ni–B for hydrogen production is comparable to that of other Ni composites.

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Language(s): eng - English
 Dates: 2011-09-302011-11-22
 Publication Status: Issued
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1016/j.catcom.2011.09.015
 Degree: -

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Title: Catalysis Communications
Source Genre: Journal
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Affiliations:
Publ. Info: Amsterdam : Elsevier
Pages: - Volume / Issue: 16 (1) Sequence Number: - Start / End Page: 120 - 123 Identifier: ISSN: 1566-7367
CoNE: https://pure.mpg.de/cone/journals/resource/110989848614006