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Abstract:
The synthesis of luminescent rod-coil diblock and coil-rod-coil triblock copolymers containing oligo(p-phenyleneethynylene) as the rodlike block and polystyrene as the coil was achieved via atom transfer radical polymerization using oligo(p- phenyleneethynylene)s as the initiators substituted with 2- halogenopropionyloxy or 4-(bromomethyl)benzyloxy groups.