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  Butadiene rubbers: topological constraints and microscopic deformation by mechanical and small angle neutron scattering investigation

Menge, H., Pyckhout-Hintzen, W., Meier, G., & Straube, E. (2002). Butadiene rubbers: topological constraints and microscopic deformation by mechanical and small angle neutron scattering investigation. Polymer Bulletin, 48(2), 183-190.

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 Urheber:
Menge, H., Autor
Pyckhout-Hintzen, W., Autor
Meier, G.1, Autor           
Straube, E., Autor
Affiliations:
1MPI for Polymer Research, Max Planck Society, ou_1309545              

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 Zusammenfassung: Results of stress-strain measurements are reported for butadiene rubbers of varying crosslink density. The fluctuation of the effective tube diameter of the polymer networks was investigated under uniaxial elongation by mechanical measurements as well as by small angle neutron scattering (SANS) which probe the local orientation on a segmental scale. The effect of topological constraints on the microscopic deformation of the butadiene network chains is well described within a tube approach. For the first time, experiments at large deformations and for polydisperse sample are presented. Excellent agreement between the statistical mechanical model and the experimental results is obtained.

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Sprache(n): eng - English
 Datum: 2002-04
 Publikationsstatus: Erschienen
 Seiten: -
 Ort, Verlag, Ausgabe: -
 Inhaltsverzeichnis: -
 Art der Begutachtung: Keine Begutachtung
 Identifikatoren: eDoc: 28483
ISI: 000175608800011
 Art des Abschluß: -

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Titel: Polymer Bulletin
  Alternativer Titel : Polym. Bull.
Genre der Quelle: Zeitschrift
 Urheber:
Affiliations:
Ort, Verlag, Ausgabe: -
Seiten: - Band / Heft: 48 (2) Artikelnummer: - Start- / Endseite: 183 - 190 Identifikator: ISSN: 0170-0839