English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
  Chemical structure and properties of plasma-polymerized maleic anhydride films

Schiller, S., Hu, J., Jenkins, A. T. A., Timmons, R. B., Sanchez-Estrada, F. S., Knoll, W., et al. (2002). Chemical structure and properties of plasma-polymerized maleic anhydride films. Chemistry of Materials, 14(1), 235-242.

Item is

Files

show Files

Locators

show

Creators

show
hide
 Creators:
Schiller, S.1, Author              
Hu, J.1, Author              
Jenkins, A. T. A.1, Author              
Timmons, R. B., Author
Sanchez-Estrada, F. S., Author
Knoll, Wolfgang1, Author              
Förch, Renate1, Author              
Affiliations:
1MPI for Polymer Research, Max Planck Society, ou_1309545              

Content

show
hide
Free keywords: -
 Abstract: Plasma-assisted polymerization of maleic anhydride has been investigated under different experimental conditions. Significant variations in the film chemical structure and the film properties were obtained using pulsed plasma depositions operated at different duty cycles. The film chemical structures were obtained using X-ray photoelectron spectroscopy (XPS) and Fourier transform infra red spectroscopy (FT-IR). Surface derivatization. reactions using decylamine and benzylamine were used to demonstrate their surface reactivity toward nucleophilic moieties and to change the surface free energy of the plasma polymer films, all of which are of particular interest for future applications in the attachment of biological molecules and cells. A method of substrate pretreatment was developed to ensure reliable binding between the substrate and the plasma polymer film in aqueous solution. Impedance spectroscopy was used to monitor polymer film changes in aqueous media. The hydrated films showed some resemblance to polyelectrolyte films and a clear correlation could be observed between the density of anhydride groups and the behavior of the films in solution.

Details

show
hide
Language(s): eng - English
 Dates: 2002-01
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: No review
 Identifiers: eDoc: 28559
ISI: 000173459300040
Other: P-02-76
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Chemistry of Materials
  Alternative Title : Chem. Mat.
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: -
Pages: - Volume / Issue: 14 (1) Sequence Number: - Start / End Page: 235 - 242 Identifier: ISSN: 0897-4756