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  Lewis base mediated autoionization of GeCl2 and SnCl2.

Singh, A. P., Roesky, H. W., Carl, E., Stalke, D., Demers, J. P., & Lange, A. (2012). Lewis base mediated autoionization of GeCl2 and SnCl2. Journal of the American Chemical Society, 134(10), 4998-5003. doi:10.1021/ja300563g.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-000F-8566-5 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0028-3B0C-0
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http://pubs.acs.org/doi/pdfplus/10.1021/ja300563g (Publisher version)
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 Creators:
Singh, A. P., Author
Roesky, H. W., Author
Carl, E., Author
Stalke, D., Author
Demers, J. P.1, Author           
Lange, A.1, Author           
Affiliations:
1Research Group of Solid-State NMR, MPI for biophysical chemistry, Max Planck Society, ou_persistent35              

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 Abstract: Cationic and anionic species of heavier low-valent group 14 elements are intriguing targets in main group chemistry due to their synthetic potential and industrial applications. In the present study, we describe the synthesis of cationic (MCl+) and anionic (MCl3–) species of heavier low-valent group 14 elements of germanium(II) and tin(II) by using the substituted Schiff base 2,6-diacetylpyridinebis(2,6-diisopropylanil) as Lewis base (LB). Treatment of LB with 2 equiv of GeCl2·dioxane and SnCl2 in toluene gives compounds [(LB)GeIICl]+[GeIICl3]− (1) and [(LB)SnIICl]+[SnIICl3]− (2), respectively, which possess each a low-valent cation and an anion. Compounds 1 and 2 are well characterized with various spectroscopic methods and single crystal X-ray structural analysis.

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Language(s): eng - English
 Dates: 2012-02-132012-03-14
 Publication Status: Issued
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 Rev. Type: Peer
 Identifiers: DOI: 10.1021/ja300563g
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Title: Journal of the American Chemical Society
Source Genre: Journal
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Pages: - Volume / Issue: 134 (10) Sequence Number: - Start / End Page: 4998 - 5003 Identifier: -