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  Direct Asymmetric α-Allylation of Aldehydes with Simple Allylic Alcohols Enabled by the Concerted Action of Three Different Catalysts

Jiang, G., & List, B. (2011). Direct Asymmetric α-Allylation of Aldehydes with Simple Allylic Alcohols Enabled by the Concerted Action of Three Different Catalysts. Angewandte Chemie International Edition, 50(40), 9471-9474. doi:10.1002/anie.201103263.

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 Creators:
Jiang, Gaoxi1, Author              
List, Benjamin1, Author              
Affiliations:
1Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445585              

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Free keywords: allylation; allylic alcohol; chiral counteranions; palladium; phosphates
 Abstract: Triple catalysis: The title reaction between α‐branched aldehydes and allylic alcohols, which generates all‐carbon quaternary stereogenic centers, constitutes the first asymmetric Tsuji–Trost‐type α‐allylation of carbonyl compounds with allylic alcohol (see scheme). This reaction is catalyzed by three different species, [Pd(PPh3)4], the chiral Brønsted acid TRIP, and benzhydryl amine.

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Language(s): eng - English
 Dates: 2011-05-122011-09-132011-09-26
 Publication Status: Published in print
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201103263
 Degree: -

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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem., Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 50 (40) Sequence Number: - Start / End Page: 9471 - 9474 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851