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  Synthesis and structural studies of some selenoureas and their metal complexes

Molter, A., Rust, J., Lehmann, C. W., & Mohr, F. (2011). Synthesis and structural studies of some selenoureas and their metal complexes. Arkivoc, (6), 10-17. doi:10.3998/ark.5550190.0012.602.

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 Creators:
Molter, Anja1, Author
Rust, Jörg2, Author           
Lehmann, Christian W.2, Author           
Mohr, Fabian1, Author
Affiliations:
1Fachbereich C - Anorganische Chemie, Bergische Universität Wuppertal, 42119 Wuppertal, Germany, ou_persistent22              
2Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625              

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Free keywords: Selenourea; NMR spectroscopy; X-ray crystal structure; metal complexes
 Abstract: The selenoureas PhC(O)NHC(Se)NPhMe, 4-MeC6H4C(O)NHC(Se)NPhMe and 4-MeC6H4C(O)-NHC(Se)NEt2 were prepared and characterized by spectroscopic methods and single crystal X-ray diffraction. 4-MeC6h4C(O)NHC(Se)NEt2 was reacted with some Pt(II), Pd(II) and Ru(II) precursers to give heteroleptic, cationic metal complexes which were characterized by NMR spectroscopy, electron mass spectrometry and, in the case of the Pd(II) complex [Pd{4-MeC6H4C(O)NC(Se)NEt2}{tBu2bipy)]PF6 by X-ray diffraction.

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Language(s): eng - English
 Dates: 2010-12-062011
 Publication Status: Issued
 Pages: 8
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.3998/ark.5550190.0012.602
 Degree: -

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Title: Arkivoc
  Alternative Title : Arkivoc
Source Genre: Journal
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Publ. Info: GAINESVILLE : ARKAT USA INC
Pages: - Volume / Issue: (6) Sequence Number: - Start / End Page: 10 - 17 Identifier: ISSN: 1551-7004