English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
Add to Basket
 Local TagsRelease HistoryDetailsSummary
  A New Class of Singlet Carbene Ligands

Alcarazo, M., Suárez, R. M., Goddard, R., & Fürstner, A. (2010). A New Class of Singlet Carbene Ligands. Chemistry – A European Journal, 16(32), 9746-9749. doi:10.1002/chem.201001779.

Item is

 

show all hide all

Basic

show hide
Item Permalink: https://hdl.handle.net/11858/00-001M-0000-000F-8D2F-7 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0028-1ABE-8
Genre: Journal Article

Files

show Files
hide Files
:
[278]SI.pdf (Supplementary material), 387KB
View   Save
File Permalink:
https://hdl.handle.net/11858/00-001M-0000-0028-1ABB-E
Name:
[278]SI.pdf
Description:
Supporting Information
OA-Status:
Visibility:
Public
MIME-Type / Checksum:
application/pdf / [MD5]
Technical Metadata:
View
Copyright Date:
-
Copyright Info:
-
License:
-

Locators

show

Creators

show
hide
 Creators:
Alcarazo, Manuel1, Author           
Suárez, Rosa M.2, Author           
Goddard, Richard3, Author           
Fürstner, Alois2, Author           
Affiliations:
1Research Group Alcarazo, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445592              
2Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445584              
3Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625              

Content

show
hide
Free keywords: allenes; carbenes; gold; rhodium; zwitterions
 Abstract: What are you? Deprotonation of fluorenylidene phosphonium salts generates reactive intermediates that can be described as push–pull cumulenes or singlet carbenes (see scheme). Whereas the NMR data are ambiguous, the coordination behavior shows the ready availability of a lone pair at the central C atom. The donor ability of singlet carbene ligands of this new class exceeds

Details

show
hide
Language(s): eng - English
 Dates: 2010-06-232010-07-292010-08-23
 Publication Status: Issued
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: eDoc: 534714
DOI: 10.1002/chem.201001779
ISI: 000281689700006
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Chemistry – A European Journal
  Other : Chem. – Eur. J.
  Other : Chem. Eur. J.
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Weinheim, Germany : VCH Verlagsgesellschaft
Pages: - Volume / Issue: 16 (32) Sequence Number: - Start / End Page: 9746 - 9749 Identifier: ISSN: 0947-6539
CoNE: https://pure.mpg.de/cone/journals/resource/954926979058