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  A New Structural Motif for Bifunctional Brønsted Acid/Base Organocatalysis

Wakchaure, V. N., & List, B. (2010). A New Structural Motif for Bifunctional Brønsted Acid/Base Organocatalysis. Angewandte Chemie International Edition, 49(24), 4136-4139. doi:10.1002/anie.201000637.

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 Creators:
Wakchaure, Vijay N.1, Author              
List, Benjamin1, Author              
Affiliations:
1Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445585              

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Free keywords: asymmetric catalysis; bifunctional catalysis; desymmetrization; organocatalysis
 Abstract: Naturally synthetic: Acid/base catalyst (S)‐1 can be used in highly enantioselective alcoholytic desymmetrizations of meso anhydrides. For example, the methanolysis of cyclobutane anhydride derivative 2 gave hemiester 3 in 99:1 e.r. (see scheme). Ester 3 was used in a short enantioselective synthesis of (+)‐grandisol.

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Language(s): eng - English
 Dates: 2010-02-022010-05-262010-06-01
 Publication Status: Published in print
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201000637
 Degree: -

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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem., Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 49 (24) Sequence Number: - Start / End Page: 4136 - 4139 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851