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  N-Phosphinyl Phosphoramide — A Chiral Brønsted Acid Motif for the Direct Asymmetric N,O-Acetalization of Aldehydes

Vellalath, S., Čorić, I., & List, B. (2010). N-Phosphinyl Phosphoramide — A Chiral Brønsted Acid Motif for the Direct Asymmetric N,O-Acetalization of Aldehydes. Angewandte Chemie International Edition, 49(50), 9749-9752. doi:10.1002/anie.201005347.

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 Creators:
Vellalath, Sreekumar1, Author              
Čorić, Ilija1, Author              
List, Benjamin1, Author              
Affiliations:
1Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445585              

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Free keywords: Brønsted acid catalysis; cyclic N,O-acetals; organocatalysis; N-phosphinyl phosphoramides
 Abstract: Fine‐tuning the sites: The readily accessible N‐phosphinyl phosphoramide 1 proved to be highly efficient and enantioselective in catalyzing the title reaction. The synthetic utility of this methodology was demonstrated with the first catalytic asymmetric synthesis of the analgesic pharmaceutical (R)‐chlorothenoxazine (see scheme).

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Language(s): eng - English
 Dates: 2010-11-092010-12-10
 Publication Status: Published in print
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201005347
 Degree: -

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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem., Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 49 (50) Sequence Number: - Start / End Page: 9749 - 9752 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851