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  Catalytic Asymmetric Epoxidation of α-Branched Enals

Lifchits, O., Reisinger, C. M., & List, B. (2010). Catalytic Asymmetric Epoxidation of α-Branched Enals. Journal of the American Chemical Society, 132(30), 10227-10229. doi:10.1021/ja1037935.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-000F-8DB5-A Version Permalink: https://hdl.handle.net/21.11116/0000-0008-4840-F
Genre: Journal Article

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 Creators:
Lifchits, Olga1, Author           
Reisinger, Corinna M.1, Author           
List, Benjamin1, Author           
Affiliations:
1Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445585              

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 Abstract: An asymmetric catalytic epoxidation of α-branched, α,β-unsaturated aldehydes is presented. A highly synergistic combination of a primary cinchona-based amine and a chiral phosphoric acid was found to promote the reaction with excellent enantiocontrol for α-monosubstituted and α,β-disubstituted enals.

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Language(s): eng - English
 Dates: 2010-05-042010-07-122010-08-04
 Publication Status: Issued
 Pages: 3
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1021/ja1037935
 Degree: -

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Title: Journal of the American Chemical Society
  Other : JACS
  Abbreviation : J. Am. Chem. Soc.
Source Genre: Journal
 Creator(s):
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Publ. Info: Washington, DC : American Chemical Society
Pages: - Volume / Issue: 132 (30) Sequence Number: - Start / End Page: 10227 - 10229 Identifier: ISSN: 0002-7863
CoNE: https://pure.mpg.de/cone/journals/resource/954925376870