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  Elementary Steps in Gold Catalysis: The Significance of gem-Diauration

Seidel, G., Lehmann, C. W., & Fürstner, A. (2010). Elementary Steps in Gold Catalysis: The Significance of gem-Diauration. Angewandte Chemie International Edition, 49(45), 8466-8470. doi:10.1002/anie.201003349.

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[281]SI.pdf (Supplementary material), 151KB
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[281]SI.pdf
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Copyright Date:
2010
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Wiley-VCH, 69451 Weinheim, Germany
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 Creators:
Seidel, Günter1, Author              
Lehmann, Christian W.2, Author              
Fürstner, Alois1, Author              
Affiliations:
1Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445584              
2Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625              

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Free keywords: boron; gold; homogeneous catalysis; reactive intermediates; structure elucidation
 Abstract: Disturbing neighbors: Alkenylgold species with a heteroatom substituent are thought to be key intermediates in gold-catalyzed trans additions of protic nucleophiles to alkynes. One reason for the scarcity of such compounds lies in the non-innocence of the neighboring heteroatom, which may enforce the uptake of a second gold fragment with formation of surprisingly robust species with a gem-digold unit adjacent to a largely cationic center.

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Language(s): eng - English
 Dates: 2010-06-022010-08-182010-11-02
 Publication Status: Published in print
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201003349
 Degree: -

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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem., Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 49 (45) Sequence Number: - Start / End Page: 8466 - 8470 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851