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  Cationic palladium(II), platinum(II) and ruthenium(II) complexes containing a chelating difluoro-substituted thiourea ligand

Pisiewicz, S., Rust, J., Lehmann, C. W., & Mohr, F. (2010). Cationic palladium(II), platinum(II) and ruthenium(II) complexes containing a chelating difluoro-substituted thiourea ligand. Polyhedron, 29(8), 1968-1972. doi:10.1016/j.poly.2010.03.010.

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 Creators:
Pisiewicz, Sabine1, Author
Rust, Jörg2, Author              
Lehmann, Christian W.2, Author              
Mohr, Fabian1, Author
Affiliations:
1Fachbereich C - Anorganische Chemie, Bergische Universität Wuppertal, 42119 Wuppertal, Germany, ou_persistent22              
2Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625              

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Free keywords: Thiourea; Chelating ligand; Palladium; Platinum; Ruthenium; X-ray structure
 Abstract: The fluorine substituted thiourea 2,6-F2C6H3C(O)NHC(S)NEt2 was prepared in good yield from the reaction of 2,6-F2C6H3C(O)Cl with KSCN and Et2NH in acetone. Using this compound several heteroleptic, monocationic Pd(II), Pt(II) and Ru(II) complexes of the type cis-[M{κ2S,O-2,6-F2C6H3C(O)NC(S)NEt2}(L)]PF6 [M = Pt, Pd; L = (Ph3P)2, tBu2bipy, 1,10-phen] as well as [Ru(η6-p-cym){κ2S,O-2,6-F2C6H3C(O)NC(S)NEt2}(PPh3)]PF6 were prepared in high yields. The compounds were characterised by spectroscopic methods and, in one case, by single crystal X-ray diffraction.

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Language(s): eng - English
 Dates: 2010-05-27
 Publication Status: Published in print
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1016/j.poly.2010.03.010
 Degree: -

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Title: Polyhedron
  Abbreviation : Polyhedron
Source Genre: Journal
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Publ. Info: Oxford : Pergamon
Pages: - Volume / Issue: 29 (8) Sequence Number: - Start / End Page: 1968 - 1972 Identifier: ISSN: 0277-5387
CoNE: https://pure.mpg.de/cone/journals/resource/954925622228_2