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  Kinetic Resolution of Homoaldols via Catalytic Asymmetric Transacetalization

Čorić, I., Müller, S., & List, B. (2010). Kinetic Resolution of Homoaldols via Catalytic Asymmetric Transacetalization. Journal of the American Chemical Society, 132(49), 17370-17373. doi:10.1021/ja108642s.

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 Creators:
Čorić, Ilija1, Author              
Müller, Steffen1, Author              
List, Benjamin1, Author              
Affiliations:
1Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445585              

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 Abstract: The highly enantioselective kinetic resolution of homoaldols via a transacetalization reaction has been achieved. A novel phosphoric acid, STRIP, based on a spirocyclic 1,1′-spirobiindane backbone was designed and identified as a superior catalyst for this transformation. Remarkably, both secondary and tertiary homoaldols gave equally excellent results.

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Language(s): eng - English
 Dates: 2010-09-242010-11-182010-12-15
 Publication Status: Published in print
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1021/ja108642s
 Degree: -

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Title: Journal of the American Chemical Society
  Other : JACS
  Abbreviation : J. Am. Chem. Soc.
Source Genre: Journal
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Publ. Info: Washington, DC : American Chemical Society
Pages: - Volume / Issue: 132 (49) Sequence Number: - Start / End Page: 17370 - 17373 Identifier: ISSN: 0002-7863
CoNE: https://pure.mpg.de/cone/journals/resource/954925376870