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Free keywords:
cascade reactions; complexe reactions; electrospray mass spectrometry; iminium catalysis; organocatalysis
Abstract:
Chemical scrabble: Mechanistic studies of complex organocatalytic cascade reactions are challenging owing to the presence of many species involved. Electrospray ionization mass spectrometry provides details about a one‐pot quadruple organocatalytic cascade reaction, and allows detailed characterization of the reaction and its key intermediates.